This potential difference is also called voltage. The SI unit of potential
difference is “Volt” and it is denoted by V.
1 Volt = 1 Joule/1 Coulomb
1V = 1J/C
• What is the direction of electric current in terms of potential
difference?
• Do positive charges move in a conductor? Can you give an example of
this?
Let us recall your experience of electrolysis and electroplating and
conductivity of fluids that you had learned in earlier classes. When electric
current is allowed to pass through fluids, the positive ions (cations) and
negative ions (anions) move in opposite directions. The direction of the
motion of positive charges in an electrolyte is always in the direction of
the electric field while negative charges move in a direction opposite to
that of positive charges. Thus for conduction in fluids there exists motion
of both positive and negative charges. Whereas in case of metal conductors
there will be only motion of electrons. (The positive charges are fixed in
the lattice)
If positive charges move from point A to B in a conductor, the electric
field does positive work so W/q is positive for free positive charges. You
can say that the direction of the electric field is from A to B and the point
A is at high potential and point B is at low potential. As negative charges
always move in a direction opposite to the electric field we consider that
electrons move from low potential to high potential.
We know that in a battery or cell a constant potential difference is
maintained till the battery is completely discharged.
• How does a battery maintain a constant potential difference between
its terminals?
• Why does the battery discharge when its positive and negative terminals
are connected through a conductor?
To answer this, we need to know about how a battery or a cell works.
A battery consists of two metal plates (electrodes) and a chemical
(electrolyte). The electrolyte (chemical) between the two metal plates
consists of positive and negative ions which move in opposite directions
(see figure 6). The electrolyte exerts a certain force on these ions and
makes them move in a specified direction. Let us call this force as a
chemical force (Fc
). Depending upon the nature of the chemical, positive
ions move towards one of the plates and accumulate on that plate. As a