excess of air. This process is known as roasting. Generally the sulphide ores are roasted to convert them into oxides before reducing them to metal.

     Eg: 2PbS + 3O2 → 2PbO + 2SO2

The metal oxides are then reduced to the corresponding metal by using suitable reducing agent such as carbon

i) Reduction of metal oxides with carbon:

oxides are reduced by coke in a closed furnace which gives the metal and carbon monoxide (CO).


     Eg: PbO + C ––>(at 1400 o C) Pb+CO

ii) Reduction of oxide ores with CO. in blast furnace

     Eg: Fe2O3+ 3CO –––>(in blast furnace) 2Fe + 3CO2


iii) Auto (self) reduction of sulphide ores:

In the extraction of Cu from its sulphide ore, the ore is subjected partial roasting in air to give its oxide.

     2Cu2 S + 3O2 J→2Cu2 O + 2SO2

When the supply of air is stopped and the temperature is raised. The rest of the sulphide reacts with oxide and forms the metal and SO2.

     2Cu2 O + Cu2 S → 6Cu + SO2

iv)Reduction of ores (compounds) by more reactive metals.

Thermite process involves the reaction of metal oxides with aluminium. When highly reactive metals such as sodium, calcium, aluminium etc., are used as reducing agents, they displace metals of lower reactivity from the compound. These displacement reactions are highly exothermic. The amount of heat evolved is so large that the metals produced are in molten state.

      Eg: TiCl4+2Mg–––––>(850 o C)Ti + 2MgCl2

      TiCl4+4Na ––––––>(850 o C)NaCL


pg no:244

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